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Textile Pollutants

The problem of wastewater from textile industry is rather complicated, since this industry uses a great variety of raw materials, intermediate products, and chemicals. Methods of production also vary widely. The quantity of wastewater discharged into sewerage per production unit is roughly 90 to 100 per cent of total water consumption for the processing.

The qualitative characteristics of wastewater are variable largely and, even in the same industry branch, depend on the use of dyestuffs and raw materials types, liquor to material ratios, and the type of machines they employ.

The two main sources of pollution in the textile process are the natural impurities extracted from the type of fibre under processing along with the chemicals used. Other factors, which determine effluent quantity and quality, include the number of operations used and the degree to which they preserve water and chemicals in a particular manufacturing plant.

Wool scouring effluents have high BOD compared to cotton finishing effluents that contain no grease and have a relatively low solids content. Synthetic finishing effluents are generally lower in volume than those generated in cotton finishing, but may contain toxic substances, especially from t hose dyeing streams where chemical dyes with a metallic ion content are used more widely. Also of particular concern are some specific compounds that are toxic to aquatic life.

According to a technical report of UNIDO the sources of major metal pollutants , i.e., zinc, copper, chromium, etc. are likely to be the dyes used in wet processing operations. The causes of air pollution attributed to textile industry are mainly from emissions from textile processing, excluding boiler emissions. Oil mist and organic emissions are produced when textile materials containing knitting and lubricating oils, platicisers, and other materials that can volatilise or be thermally degraded into volatile substances, are subjected to heat.

Processes that can be sources of oil mist include stentering, calendaring, heat setting, drying, and curing. Carbonisation of wool and some types of spray dyeing produce acid mist. Solvent processing operations such as dry cleaning and scouring releases vapours. The other cause is dust and lin t produced during the spinning of natural fibres and synthetic staple as well as by carpet shearing. Add to above be the releases of excessive nitrogen from the production and use of nitrogen fertilizers to the burning of fossil fuels in automobiles, power generation plants, and industries. This has doubled the natural annual rate at which fixed nitrogen enters the land-based nitrogen cycle, and the pace is likely to accelerate.

TextileScan_A Compendium of Textiles

Characteristic Concentrations of some contaminants in waste waters from wool, cotton and Rayon Industries

Contamination

Unit

Wool

Cotton

Rayon

   

min.

max.

mean

min.

max.

mean

min.

max.

mean

Temperature Degree Centigrade 16.0 65.0 33.9 7.0 85.0 26.0 14.0 60.0 29.0
Reaction pH value 4.6 11.0 -- 2.0 12.5 -- 2.5 12.3 --
BOD mg/litre 20.4 3600.0 372.0 17.0 9400 461.5 16.0 892.0 298.60
Detergents mg/litre 0.2 50.0 5.2 2.00 12.4 7.0 1.0 4.4 2.93
Suspensions mg/litre 316.0 14215.0 2774.0 340.0 51396.0 2775.0 274.0 3449.0 1118.00
Alkalinity mval/litre 2.2 92.0 7.9 0.7 102.5 25.6 0.5 38.0 6.80
Source: Plant and Power Engineering, Training for Industry Series No. 3, United Nations Publication, New York, 1970

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